We prove an asymptotic formula for the second moment of a product of two Dirichlet L-functions on the critical line, which has a power saving in the error term and which is uniform with respect to the involved Dirichlet characters. As special cases we give uniform asymptotic formulae for the fourth moment of individual Dirichlet L-functions and for the second moment of Dedekind zeta functions of quadratic number fields on the critical line.