A trinuclear metallasilsesquioxane of uranium(III)
Tricoire, Maxime Christian Gérard; Jori, Nadir; Tirani, Farzaneh Fadaei; Scopelliti, Rosario; Zivkovic, Ivica; Natrajan, Louise S.; Mazzanti, Marinella
2023

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Abstract

The silsesquioxane ligand (Bu-i)(7)Si7O9(OH)(3) ((POSSH3)-P-iBu) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U-3((POSS)-P-iBu)(3)]) that exhibits magnetic communication and promotes dinitrogen reduction in the presence of reducing agent.

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Title A trinuclear metallasilsesquioxane of uranium(III)
Author(s) Tricoire, Maxime Christian Gérard ; Jori, Nadir ; Tirani, Farzaneh Fadaei ; Scopelliti, Rosario ; Zivkovic, Ivica ; Natrajan, Louise S. ; Mazzanti, Marinella
Published in Chemical Communications
Volume 60
Issue 1
Pages 55-58
Date 2023-11-23
ISSN 1359-7345
1364-548X
Keywords
DOI https://doi.org/10.1039/d3cc05390c
Other identifier(s) View record in Web of Science
Dataset(s) URL: https://zenodo.org/records/10787616
Laboratories GCC
Record Appears in Scientific production and competences > SB - School of Basic Sciences > ISIC - Institute of Chemical Sciences and Engineering > GCC - Group of Coordination Chemistry
Peer-reviewed publications
Work produced at EPFL
Journal Articles
Published
Grant Swiss National Science Foundation: 212723
Ecole Polytechnique Federale de Lausanne (EPFL)
FNS: TMPFP2_217133
Record creation date 2024-02-20

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